Stewart Warner
10/01/2023 · Senior High School

Sulfuryl chloride can dissociate into sulfur dioxide and chlorine: \[ \mathrm{SO}_{2} \mathrm{Cl}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{SO}_{2}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \] At \( 100^{\circ} \mathrm{C} \), the equilibrium constant in terms of pressures, \( \mathrm{K}_{\mathrm{p}} \), for this dissociation reaction is 2.40 . (a) If 12.76 g of sulfuryl chloride is placed in a 12.67 - L vessel and heated to \( 100^{\circ} \mathrm{C} \), what is the partial pressure of sulfur dioxide when equilibrium is attained? (b) What fraction of sulfuryl chloride is dissociated at equilibrium?

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(a) The partial pressure of sulfur dioxide at equilibrium is approximately 0.21 atm. (b) The fraction of sulfuryl chloride dissociated at equilibrium is approximately 92.3%.

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